Efficient CO2 adsorption by deoiled flaxseed hydrochar

Abstract

Abstract This study optimizes CO2 adsorption using hydrochar from de-oiled flaxseed (FDOP), a waste byproduct of the oil extraction industry, through hydrothermal carbonization (HTC). The aim is to enhance CO2 capture sustainably and cost-effectively. Using Response Surface Methodology (RSM), in optimal conditions achieved 1153.26 mg/g CO2 adsorption capacity under 215.15 °C synthesis temperature, 3.05 h synthesis time, 0.99 M acid concentration, 8.997 bar pressure, and 25.07 °C adsorption temperature. Statistical analysis (F-value: 44.48, R²: 0.9705) confirmed strong model reliability. Kinetic analysis showed both physical and chemical adsorption, while thermodynamic analysis revealed exothermic behavior (ΔH° values: -46.697 kJ/mol for M-225, -40.230 kJ/mol for MA-203). After 10 regeneration cycles, the adsorption capacity was reduced by only 2.8% and 3.1%, indicating excellent recyclability. This study highlights FDOP-derived hydrochar as a highly efficient, low-cost adsorbent, offering industrial applications for carbon capture and waste management.

Keywords

• Hydrochar
• CO2 adsorption
• Hydrothermal carbonization
• RSM