Acta Crystallographica Section E (Jul 2012)

Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ2N,O}copper(II)

  • M. Sukeri M. Yusof,
  • Maisara A. Kadir,
  • Bohari M. Yamin

DOI
https://doi.org/10.1107/S1600536812025081
Journal volume & issue
Vol. 68, no. 7
pp. m894 – m894

Abstract

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In the centrosymmetric mononuclear title complex, [Cu(C18H20N2O2)2], the CuII atom is four-coordinated in a trans-CuN2O2 square-planar geometry with the N—Cu—O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methylbenzene and 2,4-dimethylbenzene fragments with the plane defined by the chelate ring are 13.43 (15) and 82.69 (13)° respectively. The angle between the planes defined by the aromatic carbons of the two rings is 89.40 (16)°. A a weak intramolecular C—H...N hydrogen bond occurs.