Nanomaterials (May 2020)

Nanoporous Carbon Derived from Green Material by an Ordered Activation Method and Its High Capacitance for Energy Storage

  • Qingjie Lu,
  • Shiqiang Zhou,
  • Yumin Zhang,
  • Mingpeng Chen,
  • Bo Li,
  • Haitang Wei,
  • Dongming Zhang,
  • Jin Zhang,
  • Qingju Liu

DOI
https://doi.org/10.3390/nano10061058
Journal volume & issue
Vol. 10, no. 6
p. 1058

Abstract

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Carbon materials have been widely used as electrode materials for supercapacitors, while the current carbon precursors are mainly derived from fossil fuels. Biomass-derived carbon materials have become new and effective materials for electrodes of supercapacitors due to their sustainability, low pollution potential, and abundant reserves. Herein, we present a new biomass carbon material derived from water hyacinth by a novel activation method (combination of KOH and HNO3 activation). According to the electrochemical measurements, the material presents an ultrahigh capacitance of 374 F g−1 (the current density is 1 A g−1). Furthermore, the material demonstrates excellent rate performance (105 F g−1 at a higher density of 20 A g−1) and ideal cycling stability (87.3% capacity retention after 5000 times charge–discharge at 2 A g−1). When used for a symmetrical supercapacitor device, the material also shows a relatively high capacity of 330 F g−1 at 1 A g−1 (a two-electrode system). All measurements suggest the material is an effective and noteworthy material for the electrodes of supercapacitors.

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