Using Sawdust Derived Biochar as a Novel 3D Particle Electrode for Micropollutants Degradation

Abstract

This work examined the use of a 3D combined electrochemical process based on particle electrodes from sawdust-derived biochar pyrolized at T = 550–850 °C to remove persistent pollutants. The as-prepared biochar was characterized by scanning electron microscopy with an X-ray energy dispersive spectrometer (SEM/EDS), nitrogen adsorption (BET method) and X-ray diffraction (XRD) techniques. The use of sawdust biochar pyrolized at 650 °C led to a significant increase in efficiency against the sum of conventional 2D electrochemical systems and adsorption, and the synergy index estimated equal to 74.5% at optimum conditions. Sulfamethoxazole (SMX) removal was favored by increasing particle electrode loading. Despite that, the reaction was slightly favored in near-neutral conditions; the system retained most of its activity in the pH range 3–10. The proposed 3D system could degrade different micropollutants, namely SMX, Bisphenol A (BPA), Propylparaben (PP), and Piroxicam (PR). Of particular interest was that no significant reduction in degradation was observed in the case of complex or real water matrices. In addition, the system retained its efficiency regarding SMX removal after five sequential experiments in the 3D combined electrochemical process. However, further investigation is needed to estimate the contribution of the different mechanisms of micropollutant removal in the proposed system.

Keywords

• three-dimensional electrochemical process
• novel particle electrode
• biochar
• micropollutants
• synergy