Precise electrical gating of the single-molecule Mizoroki-Heck reaction

Lei Zhang; Chen Yang; Chenxi Lu; Xingxing Li; Yilin Guo; Jianning Zhang; Jinglong Lin; Zhizhou Li; Chuancheng Jia; Jinlong Yang; K. N. Houk; Fanyang Mo; Xuefeng Guo

doi:10.1038/s41467-022-32351-8

Nature Communications (Aug 2022)

Precise electrical gating of the single-molecule Mizoroki-Heck reaction

Lei Zhang,
Chen Yang,
Chenxi Lu,
Xingxing Li,
Yilin Guo,
Jianning Zhang,
Jinglong Lin,
Zhizhou Li,
Chuancheng Jia,
Jinlong Yang,
K. N. Houk,
Fanyang Mo,
Xuefeng Guo

Affiliations

Lei Zhang: Beijing National Laboratory for Molecular Sciences, National Biomedical Imaging Centre, College of Chemistry and Molecular Engineering, Peking University
Chen Yang: Beijing National Laboratory for Molecular Sciences, National Biomedical Imaging Centre, College of Chemistry and Molecular Engineering, Peking University
Chenxi Lu: Department of Chemistry and Biochemistry, University of California
Xingxing Li: Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China
Yilin Guo: Beijing National Laboratory for Molecular Sciences, National Biomedical Imaging Centre, College of Chemistry and Molecular Engineering, Peking University
Jianning Zhang: School of Materials Science and Engineering, Peking University
Jinglong Lin: School of Materials Science and Engineering, Peking University
Zhizhou Li: Beijing National Laboratory for Molecular Sciences, National Biomedical Imaging Centre, College of Chemistry and Molecular Engineering, Peking University
Chuancheng Jia: Centre of Single-Molecule Sciences, Institute of Modern Optics, Frontiers Science Centre for New Organic Matter, College of Electronic Information and Optical Engineering, Nankai University
Jinlong Yang: Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China
K. N. Houk: Department of Chemistry and Biochemistry, University of California
Fanyang Mo: School of Materials Science and Engineering, Peking University
Xuefeng Guo: Beijing National Laboratory for Molecular Sciences, National Biomedical Imaging Centre, College of Chemistry and Molecular Engineering, Peking University

DOI: https://doi.org/10.1038/s41467-022-32351-8
Journal volume & issue: Vol. 13, no. 1
pp. 1 – 11

Abstract

Read online

Guiding chemical reactions in a predictable and controllable manner is an ultimate goal of chemistry. Here, the authors show tuning of the single-molecule Mizoroki-Heck catalytic cycle through electrical gating and direct in-situ detection.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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