L-lysine and surfactant-assisted synthesis of NiCo bimetal oxides for electrochemical water splitting

Abstract

Summary: In the present study, bimetallic oxides comprising nickel (Ni) and cobalt (Co) were synthesized using a facile hydrothermal method in the presence of CTAB and L-lysine. Their efficacy in catalyzing hydrogen production under alkaline conditions was assessed. Structural, vibrational, and morphological characteristics were analyzed utilizing X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM) techniques. The SEM images revealed a needle-like shape which is due to the surfactant addition. The NiCo oxides exhibited the lowest onset potential of 83 mV for HER and 130 mV for OER under standard conditions. The catalysts needed a potential of 286 and 450 mV to attain a current density of 50 mA/cm2 along with Tafel slope values of 119 and 332 mV/dec for HER and OER, respectively. These results suggested that L-lysine as a surfactant is highly effective in the fabrication of NiCo bimetal oxides for electrolytic water splitting applications.

Keywords

• Natural sciences
• Chemistry
• Applied sciences