Properties of Composite Powder Based on Boron Nitride Prepared under Concentrated Light

Abstract

The results of direct synthesis of composite powder based on boron nitride (BN) are considered. Concentrated light heating of the initial boron powder was carried out in a xenon high-flux optical furnace in a nitrogen flow. Formation of particles of the desired sizes and architecture highly dependent of the synthesis conditions. The flow of nitrogen separates the particles depending on their architecture and size. An increase in the distance from the reaction zone leads to the formation of powder with a wider bandgap, increases the amount of amorphous phase, and decreases the amount of oxide in the collected composite powder. However, the close distance to the reaction zone and high temperatures provide a denser packing of the structure on the particle surface and the disappearance of the BN transition phases. Incorporation of the nickel sulfate hexahydrate to initial boron contributes to the formation of graphene-like structures.

Keywords

• flux synthesis
• vapor deposition
• nanostructures
• boron nitride
• optical properties
• architecture of nanostructures