International Journal of Photoenergy (Jan 2013)

Catalytic Activity of Porous Phosphate Heterostructures-Fe towards Reactive Black 5 Degradation

  • Marco S. Lucas,
  • Manuel Algarra,
  • José Jiménez-Jiménez,
  • Enrique Rodríguez-Castellón,
  • José A. Peres

DOI
https://doi.org/10.1155/2013/658231
Journal volume & issue
Vol. 2013

Abstract

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Fenton’s reaction is often used to decompose stable substances in wastewater. In this study, experiments based on the effect of porous phosphate heterostructures as catalyst sorbent of Fe2+ synthesised by different procedures were planned. The examined PPH-Fe/H2O2 as oxidant in a heterogeneous process under mild conditions at pH 5 was found to be very efficient for discoloration of a simulated wastewater containing 50 mg L−1 of a commercial azo dye (Reactive Black 5) reaching 95% of decolourization. Under the described conditions total visual decolourization was achieved after 360 min. This study can provide a simple, effective, and economic system ideal for the treatment of toxic and nonbiodegradable azo dyes.