Carbon-deficient high-entropy (Zr0.17Nb0.2Ta0.2Mo0.2W0.2)C0.89: A potential high temperature and vacuum wear-resistant material

Abstract

High-entropy carbides are promising materials as sliding structural components in ultra-high temperature environments due to their good phase stability and excellent mechanical properties. However, the tribological behaviors under coupling conditions of high temperature and vacuum environment have not been deeply evaluated. To fill such a gap, the high-temperature tribological properties of carbon-deficient high-entropy (Zr0.17Nb0.2Ta0.2Mo0.2W0.2)C0.89 (HEC0.89) prepared by using five binary carbides (ZrC, NbC, TaC, Mo2C, and WC) as starting materials were investigated. The microhardness and fracture toughness of HEC0.89 were 21.3 ± 0.5 GPa and 4.5 ± 0.2 MPa·m1/2. Most importantly, HEC0.89 exhibited low wear rate (lower than an order of 10-6 mm3/Nm) under vacuum environments from room temperature (RT) to high temperatures. Moreover, the lowest friction coefficient (0.31 ± 0.01) was obtained at 900 °C, which is attributed to the transferring of films consisting of low hardness oxidation products. These results clearly demonstrate the prospective for the application of high-entropy carbides as sliding parts in high-temperature and vacuum environments.

Keywords

• High-entropy ceramics
• Transition metal carbides
• Carbon stoichiometry deviation
• High temperature under vacuum environment
• Tribological performances