Rambutan‐like hierarchically porous carbon microsphere as electrode material for high‐performance supercapacitors
Chunfeng Shao,
Shujun Qiu,
Guiming Wu,
Boyang Cui,
Hailiang Chu,
Yongjin Zou,
Cuili Xiang,
Fen Xu,
Lixian Sun
Affiliations
Chunfeng Shao
Guangxi Key Laboratory of Information Materials School of Materials Science and Engineering, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials Guilin University of Electronic Technology Guilin China
Shujun Qiu
Guangxi Key Laboratory of Information Materials School of Materials Science and Engineering, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials Guilin University of Electronic Technology Guilin China
Guiming Wu
Guangxi Key Laboratory of Information Materials School of Materials Science and Engineering, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials Guilin University of Electronic Technology Guilin China
Boyang Cui
Guangxi Key Laboratory of Information Materials School of Materials Science and Engineering, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials Guilin University of Electronic Technology Guilin China
Hailiang Chu
Guangxi Key Laboratory of Information Materials School of Materials Science and Engineering, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials Guilin University of Electronic Technology Guilin China
Yongjin Zou
Guangxi Key Laboratory of Information Materials School of Materials Science and Engineering, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials Guilin University of Electronic Technology Guilin China
Cuili Xiang
Guangxi Key Laboratory of Information Materials School of Materials Science and Engineering, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials Guilin University of Electronic Technology Guilin China
Fen Xu
Guangxi Key Laboratory of Information Materials School of Materials Science and Engineering, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials Guilin University of Electronic Technology Guilin China
Lixian Sun
Guangxi Key Laboratory of Information Materials School of Materials Science and Engineering, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials Guilin University of Electronic Technology Guilin China
Abstract Used as high‐performance electrodes, both structural and compositional alterations of carbon materials play very important roles in energy conversion/storage devices. Especially in supercapacitors, hierarchical pores and heteroatom doping in carbon materials are indispensable. Here the rambutan‐like hierarchically porous carbon microspheres (PCMs) have been constructed via a hydrothermal treatment, followed by carbonization/activation. The hierarchically porous microstructure is composed of three‐dimensional porous carbon networks, which give rise to a large surface area. Moreover, N and O functional groups are introduced in the as‐prepared samples, which could generate the extra pseudocapacitance. Benefitting from the interconnected hierarchical and open structure, PCM exhibits outstanding capacitive performance, for example, superior specific capacitance and rate capability (397 and 288 F g−1 at 0.5 and 20 A g−1, respectively), as well as long cycling stability (about 95% capacitance retention after 10,000 cycles). These encouraging results may pave an efficient way to fabricate advanced supercapacitors in the future.
