Comparisons of Dy Utilization Efficiency by DyH<sub>x</sub> Grain Boundary Addition and Surface Diffusion Methods in Nd-Y-Fe-B Sintered Magnet
Shuai Guo,
Shicong Liao,
Xiaodong Fan,
Guangfei Ding,
Bo Zheng,
Renjie Chen,
Aru Yan
Affiliations
Shuai Guo
CISRI & NIMTE Joint Innovation Center for Rare Earth Permanent Magnets, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
Shicong Liao
Key Laboratory of Magnetic Materials and Devices, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
Xiaodong Fan
CISRI & NIMTE Joint Innovation Center for Rare Earth Permanent Magnets, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
Guangfei Ding
CISRI & NIMTE Joint Innovation Center for Rare Earth Permanent Magnets, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
Bo Zheng
CISRI & NIMTE Joint Innovation Center for Rare Earth Permanent Magnets, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
Renjie Chen
CISRI & NIMTE Joint Innovation Center for Rare Earth Permanent Magnets, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
Aru Yan
CISRI & NIMTE Joint Innovation Center for Rare Earth Permanent Magnets, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
Using the heavy rare earth Dy element to improve coercivity is the most common solution for hindering the reduction in magnetic properties in the Nd–Fe–B magnet, and the effective utilization of Dy has become the focus of research in industrial society. In this work, we investigated the influence of DyHx addition and diffusion methods on the microstructure, magnetic performance, and thermal stability of the Nd–Y–Fe–B magnet with a Y-rich core structure. The coercivity of the DyHx addition magnet increases from 9.45 kOe to 15.51 kOe when adding 1.6 wt.% DyHx, while the DyHx diffusion magnet increases to 15.15 kOe. According to the analysis of the microstructure and elemental distribution, both Dy-rich shells were basically formed due to the diffusion process of Dy atoms. The Dy-rich shell in the DyHx addition magnet was similar with the original core–shell structure in the Nd–Y–Fe–B magnet. However, the distinct dual-shell structure consisting of a thinner Dy-rich shell and a Y-lean shell was constructed in the DyHx diffused magnet, contributing to the superior coercivity increment and Dy utilization efficiency. Furthermore, the remanence of the DyHx diffused magnet is up to 12.90 kG, which is better than that of the DyHx addition magnet (12.59 kG), due to fewer Dy atoms entering the 2:14:1 matrix grain to cause the antiferromagnetic coupling with Fe atoms. Additionally, the thermal stability of the DyHx diffusion magnet is also better than that of the DyHx addition magnet, owing to the elevated coercivity at room temperature, which expands the application range of the Nd–Y–Fe–B magnet to a certain extent.