Acta Crystallographica Section E (Nov 2011)

μ4-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe)

  • Yao-Cheng Shi,
  • Huan-Ren Cheng,
  • Li-Min Yuan,
  • Qian-Kun Li

DOI
https://doi.org/10.1107/S1600536811041936
Journal volume & issue
Vol. 67, no. 11
pp. m1534 – m1534

Abstract

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The fused bis-butterfly-shaped title compound, [Fe4(CS4)(CO)12], possesses an orthothiocarbonate (CS44−) ligand that acts as a bridge between two Fe2(CO)6 units. A short intramolecular S...S contact [2.6984 (8) and 2.6977 (8) Å] occurs in each S2Fe2(CO)6 fragment.