Investigation of temperature gradient effects and effective thermal inertia during adiabatic decomposition of substances with varying exothermic characteristics

Abstract

To further study adiabatic parameters distortion, the adiabatic decomposition of 2,4-DNT, 20%DTBP, and 45%Glucose was systematically analyzed using thermal analysis calorimetry and numerical simulation methods. The study revealed the variation laws and influence mechanisms of the temperature gradient effects and thermal inertia in adiabatic systems. A numerical model for decomposition in a closed adiabatic system was developed by integrating the apparent kinetics into the CFD code. The results show that the temperature gradient effects during adiabatic decomposition initially increase and then decrease until reaching zero. The temperature gradient effects become more pronounced as the exothermic characteristics of substances increase. They are the most significant at the peak self-heating rate, with gradients of 182.4 °C·cm−1, 21.6 °C·cm−1, and 0.78 °C·cm−1, respectively. Specific data segments for adiabatic analysis should maintain α values below 0.138 for 2,4-DNT, 0.484 for 20%DTBP, and should utilize complete 100 % adiabatic data for 45%Glucose, aiming to mitigate potential distortion in adiabatic parameters. Furthermore, Фeff varies with the reaction, initially increasing and then decreasing in deviation from the theoretical value, with peak deviations of 60 %, 20 %, and 0.3 % for three substances, respectively. These findings lay the foundation for further optimizing the temperature gradient effects and establishing a dynamic Фeff correction model.

Keywords

• Thermal analysis calorimetry
• Adiabatic decomposition
• Numerical simulation
• Temperature gradient
• Effective thermal inertia