Acta Crystallographica Section E (Apr 2008)

cis-Bis(2,2′-bipyridyl)dicyanatocobalt(II)

  • Da-Cheng Li,
  • Ling-Qian Kong,
  • LI Jia

DOI
https://doi.org/10.1107/S1600536808007617
Journal volume & issue
Vol. 64, no. 4
pp. m582 – m582

Abstract

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In the title complex, [Co(NCO)2(C10H8N2)2], the Co atom is coordinated by four N atoms from two 2,2′-bipyridyl ligands and two N atoms from two cyanate anions in a distorted octahedral geometry. The Co atom lies on a twofold rotation axis. The average Co—N bond length is 2.126 (7) Å. Weak intermolecular C—H...O interactions lead to the formation of a three-dimensional network.