Investigation of a novel multigeneration system driven by an ammonia-methane Brayton cycle with partial production and utilization of ammonia, methane, and hydrogen: Energy and carbon footprint assessments

Abstract

In this paper, to address gaps in the development of low-carbon energy systems, an innovative concept of an ammonia-methane Brayton cycle is proposed. This system is interconnected with various subsystems, including the Kalina cycle, high-temperature steam electrolysis, thermoelectric generators, and ammonia and methane synthesis reactors. The primary aim of this system was to reduce dependence on external resources by establishing local sources for water and fuel, thus reducing the environmental impact and enhancing energy sustainability. A thermodynamic model of an energy system was developed via EES codes which leads to a thoughtful perception into the interactions of the proposed system parameters. Also, comprehensive investigations involved the examination of different energy system scenarios. Modeling outputs of the proposed multigeneration system discovered excellent thermal efficiency and power production, with figures of 56.5 % and 17 MW, respectively, while the Brayton system showed the results of 23.7 % and 3.8 MW. This study also highlighted the environmental benefits of the multigeneration system by demonstrating a carbon dioxide emission of 0.058 kg/kWh, representing its significant positive impact on environmental sustainability. Also, the produced ammonia and methane within the system was 0.37 % and 9 %, of fuel in combustion chamber, respectively. Also, the rest of demand fuel was provided from the external resources.

Keywords

• Multigeneration
• Ammonia-methane
• Methanation reaction
• Ammonia synthesis reaction
• Hydrogen production