Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation
Stefan Isenberg,
Stefan Weller,
Denis Kargin,
Prof. Dr. Srećko Valić,
Dr. Brigitte Schwederski,
Dr. Zsolt Kelemen,
Dr. Clemens Bruhn,
Kristijan Krekić,
Dr. Martin Maurer,
Christoph M. Feil,
Dr. Martin Nieger,
Prof. Dr. Dr. h.c. Dietrich Gudat,
Prof. Dr. László Nyulászi,
Prof. Dr. Rudolf Pietschnig
Affiliations
Stefan Isenberg
Institute for Chemistry and CINSaT University of Kassel Heinrich Plett-Straße 40 34132 Kassel Germany
Stefan Weller
Institute for Inorganic Chemistry University of Stuttgart Pfaffenwaldring 55 70550 Stuttgart Germany
Denis Kargin
Institute for Chemistry and CINSaT University of Kassel Heinrich Plett-Straße 40 34132 Kassel Germany
Prof. Dr. Srećko Valić
Ruđer Bošković Institute Bijenička cesta 54 10000 Zagreb Croatia
Dr. Brigitte Schwederski
Institute for Inorganic Chemistry University of Stuttgart Pfaffenwaldring 55 70550 Stuttgart Germany
Dr. Zsolt Kelemen
Institute for Chemistry and CINSaT University of Kassel Heinrich Plett-Straße 40 34132 Kassel Germany
Dr. Clemens Bruhn
Institute for Chemistry and CINSaT University of Kassel Heinrich Plett-Straße 40 34132 Kassel Germany
Kristijan Krekić
Institute for Chemistry and CINSaT University of Kassel Heinrich Plett-Straße 40 34132 Kassel Germany
Dr. Martin Maurer
Institute for Chemistry and CINSaT University of Kassel Heinrich Plett-Straße 40 34132 Kassel Germany
Christoph M. Feil
Institute for Inorganic Chemistry University of Stuttgart Pfaffenwaldring 55 70550 Stuttgart Germany
Dr. Martin Nieger
Department of Chemistry University of Helsinki P.O Box 55 Helsinki 00014 Finland
Prof. Dr. Dr. h.c. Dietrich Gudat
Institute for Inorganic Chemistry University of Stuttgart Pfaffenwaldring 55 70550 Stuttgart Germany
Prof. Dr. László Nyulászi
Department of Inorganic and Analytical Chemistry and MTA-BME Computation Driven Chemistry Research Group Budapest University of Technology and Economics Szent Gellért tér 4 1111 Budapest Hungary
Prof. Dr. Rudolf Pietschnig
Institute for Chemistry and CINSaT University of Kassel Heinrich Plett-Straße 40 34132 Kassel Germany
Abstract A series of bis‐[3]ferrocenophanes of the general type Fe(C5H4E’)2E−E(E'C5H4)2Fe (E=P, SiH and E’=PtBu, NneoPentyl, NSi(CH3)3) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X‐ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations.
