Sol-gel mediated synthesis and characterization of hierarchically porous Fe2O3/SiO2 monolithic catalyst for high temperature sulfuric acid decomposition

Abstract

To address the issues faced by microparticulate catalysts in fixed bed reactors for high temperature sulfuric acid decomposition viz. channeling and mass transfer, we report the preparation, characterization of Fe2O3/SiO2 hierarchical porous monoliths and testing of its catalytic properties. Monoliths with varying Fe2O3 amounts (5–30 wt%) are synthesized by a modified sol-gel approach and characterized by powder XRD, Mössbauer spectroscopy, SAXS, SEM-EDS and XPS. The Fe2O3(15 wt%)/SiO2 monolith exhibited a SO2 yield of ∼62% at 800 °C. The spent catalyst investigation established the dynamic nature of catalyst surface to accomplish the reaction mechanistic demands.

Keywords

• Fe2O3/SiO2
• Hierarchically porous
• Monolith
• Sulfuric acid decomposition
• Hydrogen generation