Composite Layered Double Hydroxide Zn-Al/Magnetic Biochar Modified for Highly Effective Malachite Green Adsorption

Abstract

One of the main needs of humans is water, one source of water pollutantion is from dyes. Adsorption is the most popular method in removing pollutants as it is proven to be efficient. One of the dyes harmful to living things is malachite green. In this study, malachite green dye was removed using a layered double hydroxide (LDH) Zn-Al/magnetic biochar composite. The XRD, FTIR, BET, and VSM analyses show that the LDH Zn-Al, magnetic biochar, and LDH Zn-Al/magnetic biochar composite were successfully produced. The surface area of the Zn-Al/magnetic biochar composite made up of LDH increased from 9.621 m2/g to 99.473 m2/g. The point of zero charge of LDH Zn-Al and magnetic biochar were at pH 6, whereas the composite of these two materials was at pH 7. For LDH Zn-Al, magnetic biochar, and composite LDH Zn-Al/magnetic biochar, pH 8 is the ideal value for adsorption of malachite green. PSO (pseudo-second order) kinetics is the best-fit model. LDH Zn-Al, magnetic biochar, and LDH Zn-Al/magnetic biochar composite had adsorption capacities of 14.472, 15.552, and 25.907 mg/g, respectively, at a temperature of 60°C. Regeneration showed the LDH Zn-Al/magnetic biochar composite had superior and more effective ability compared to LDH Zn-Al and magnetic biochar.

Keywords

• composite
• malachite green
• magnetic
• biochar
• layered double hydroxide
• regeneration