Effect of Wet Deposition on Secondary Inorganic Aerosols Using an Urban-Scale Air Quality Model

Abstract

We investigated the effects of wet deposition on secondary inorganic aerosols (SIAs) in urban areas by coupling the wet deposition module with the three-dimensional computational fluid dynamics atmospheric chemistry model (CFD-Chem). We developed a wet deposition model for the microscale model by improving on the global modeling initiative scheme. We evaluated the model by comparing it to the observed washout ratio from the total wet deposition. The simulated washout ratio calculated using the wet scavenging coefficient (WSC) based on the theoretical calculation is six times lower than that observed, suggesting that the wet deposition amount of SIAs from below-cloud scavenging might be underestimated. When we applied the WSC based on field measurements, the washout ratio was much improved; however, it was slightly overestimated compared to the observed rate. Therefore, we estimated the optimal WSC for SIAs in the urban area using a linear regression approach. We conducted a model using the wet deposition of SIAs in a megacity to understand the effects of wet deposition on the SIA concentration using estimated optimal WSCs. The simulated results indicate that washout processes decrease the surface aerosol concentration, showing that reductions in the average surface concentrations from washout processes were from 7.1% to 11.2%. The simulation results suggest that washout processes can reduce the particulate matter concentration in urban areas, indicating that washout processes should be considered in the microscale model, although the modeling domain can only simulate washout processes.

Keywords

• secondary inorganic aerosols (SIAs)
• wet deposition
• wet scavenging coefficient (WSC)
• computational fluid dynamics (CFD) model
• urban-scale air quality modeling