Heliyon (Mar 2024)
Selective recovery of copper from copper tailings and wastewater using chelating resins with bis-picolylamine functional groups
Abstract
Industrial and mining wastewater, along with copper tailings, are typically highly acidic and contain copper and other heavy metals, which may contaminate and damage the environment. Copper (Cu) is, however, a valuable metal, making its removal and recovery from such wastewater and tailings environmentally and economically advantageous. Chelating ion exchange resins featuring bis-picolylamine functional groups are especially suitable for application requiring selective recovery of Cu(II) from highly acidic media. In this study, and for the first time, the kinetics, binding capacity and selectivity of Lewatit MDS TP 220 chelating resin towards Cu(II) are reported. The resin was characterized by Zeta potential, scanning electron microscope (SEM), Fourier-transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). Factors including pH, initial concentration, contact time, temperature, and selectivity were investigated to assess the adsorption performance of the chelating resin. The adsorption kinetics tests revealed fast adsorption within the first 5–30 min and fitted the pseudo-second-order model, signifying chemisorption process. The adsorption isotherm followed the Langmuir model, implying monolayer adsorption process. The maximum adsorption capacity (qm) for Cu(II) determined by the Langmuir model was 103.9 mg/g. The adsorption thermodynamics showed an endothermic and spontaneous adsorption. FTIR and XPS studies suggested coordination or chelation as the possible adsorption mechanism. Lewatit MDS TP 220 exhibited excellent Cu(II) adsorption, desorption with 2 M ammonium hydroxide (NH4OH), and selectivity in multi-metal ions solution. Additionally, the resin demonstrated excellent reusability after five regeneration steps. This chelating resin is a potential adsorbent for effective and recurrent recovery of Cu(II) from copper tailings and wastewater, thereby contributing to environmental remediation.
