5,7,12,14-Tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvate

Mohammad Nozari; Manpreet Kaur; Jerry P. Jasinski; Anthony W. Addison; Ahmad Arabi Shamsabadi; Masoud Soroush

doi:10.1107/S2414314616011305

IUCrData (Jul 2016)

5,7,12,14-Tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvate

Mohammad Nozari,
Manpreet Kaur,
Jerry P. Jasinski,
Anthony W. Addison,
Ahmad Arabi Shamsabadi,
Masoud Soroush

Affiliations

Mohammad Nozari: Department of Chemistry, Drexel University, 3141 Chestnut St, Philadelphia, PA 19104, USA
Manpreet Kaur: Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA
Jerry P. Jasinski: Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA
Anthony W. Addison: Department of Chemistry, Drexel University, 3141 Chestnut St, Philadelphia, PA 19104, USA
Ahmad Arabi Shamsabadi: Department of Chemical and Biological Engineering, Drexel University, 3141 Chestnut St, Philadelphia, PA 19104, USA
Masoud Soroush: Department of Chemical and Biological Engineering, Drexel University, 3141 Chestnut St, Philadelphia, PA 19104, USA

DOI: https://doi.org/10.1107/S2414314616011305
Journal volume & issue: Vol. 1, no. 7
p. x161130

Abstract

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The crystal lattice of the title compound, C34H22O2·2C3H7NO, at 173 K has monoclinic (P21/n) symmetry. Molecules are located on crystallographic centers of symmetry and have approximate non-crystallographic mmm symmetry, indicating that in solution the chemical and spectroscopic behavior would be that of a D2h molecule. The compound has applications in gas-separation membranes fabricated from polymers of intrinsic microporosity (PIM). The compound is the product of reduction of the corresponding quinone by Na2S2O4 in DMF/NaHCO3.

Published in IUCrData

ISSN: 2414-3146 (Online)
Publisher: International Union of Crystallography
Country of publisher: United Kingdom
LCC subjects: Science: Chemistry: Crystallography
Website: https://iucrdata.iucr.org

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