Acta Crystallographica Section E (Oct 2009)

(E)-N′-(3,4-Dimethoxybenzylidene)-2,4-dihydroxybenzohydrazide methanol solvate

  • Qiao-Ling Zhang,
  • Li-Zi Yin,
  • Xu-Ming Deng,
  • Song-Cai Liu,
  • De-Guang Song

DOI
https://doi.org/10.1107/S1600536809035752
Journal volume & issue
Vol. 65, no. 10
pp. o2392 – o2393

Abstract

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The title compound, C16H16N2O5·CH3OH, was obtained from a condensation reaction of 3,4-dimethoxybenzaldehyde and 2,4-dihydroxybenzohydrazide. The non-H atoms of the Schiff base molecule are approximately coplanar (r.m.s. deviation = 0.043 Å) and the dihedral angle between the two benzene rings is 1.6 (1)°. The molecule adopts an E configuration with respect to the C=N double bond. An intramolecular O—H...O hydrogen bond is observed. The Schiff base and methanol molecules are linked into a two-dimensional network parallel to (10overline{1}) by intermolecular N—H...O, O—H...N and O—H...O hydrogen bonds.