Acta Crystallographica Section E (Jan 2008)

{4,4′-Dimethoxy-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenolato}copper(II)

  • Yin-Xia Sun,
  • Su-Xia Gao,
  • Jun-Yan Shi,
  • Wen-Kui Dong

DOI
https://doi.org/10.1107/S1600536807061752
Journal volume & issue
Vol. 64, no. 1
pp. m226 – m226

Abstract

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The title complex, [Cu(C18H18N2O6)], was synthesized by the reaction of copper(II) acetate monohydrate with the ligand 4,4′-dimethoxy-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol (H2L). The Cu atom is coordinated by two O atoms and two N atoms of the L2− unit. A bridged dimer is formed through intermolecular Cu...O interactions [Cu...O = 1.9408 (15) Å], creating a distorted square-pyramidal geometry about the Cu atoms.