Acta Crystallographica Section E (Feb 2009)

Chloridobis[diphenylglyoximato(1–)-κ2N,N′](1H-imidazole-κN3)cobalt(III) hemihydrate

  • A. Dayalan,
  • C. Revathi,
  • P. Meera

DOI
https://doi.org/10.1107/S160053680804347X
Journal volume & issue
Vol. 65, no. 2
pp. m140 – m141

Abstract

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The Co centre in the title compound, [Co(C14H11N2O2)2Cl(C3H4N2)]·0.5H2O, shows a slightly distorted octahedral coordination geometry. The glyoximate units of the molecule are linked by O—H...O hydrogen bonds with the H atom almost in the middle of the two O atoms. The crystal packing is stabilized through intermolecular N—H...O, N—H...N and O—H...Cl hydrogen bonds. The uncoordinated water molecule shows half-occupation.