Acta Crystallographica Section E (Sep 2008)

Bis(μ-biphenyl-2,2′-dicarboxylato)bis[(2,2′-bipyridine)copper(II)]

  • Xi-Zhong Li,
  • Qing-Hua Wang,
  • Bin Lin,
  • Min Liang,
  • Hong-Xu Guo

DOI
https://doi.org/10.1107/S160053680802583X
Journal volume & issue
Vol. 64, no. 9
pp. m1171 – m1172

Abstract

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The title compound, [Cu2(C14H8O4)2(C10H8N2)2], is a centrosymmetric binuclear copper(II) complex, with a Cu...Cu separation of 6.136 (16) Å. The Cu atom displays a cis-CuN2O2 square-planar geometry, although two long (> 2.43 Å) Cu...O contacts complete a distorted cis-CuN2O4 octahedron. Extensive C—H...O hydrogen bonds link the molecules into a three-dimensional network.