Ceramics (Feb 2023)

High-Strength Optical Coatings for Single-Crystal ZnGeP<sub>2</sub> by the IBS Method Using Selenide and Oxide Materials

  • Mikhail Zinovev,
  • Nikolay N. Yudin,
  • Vladimir Kuznetsov,
  • Sergey Podzyvalov,
  • Andrey Kalsin,
  • Elena Slyunko,
  • Alexey Lysenko,
  • Denis Vlasov,
  • Houssain Baalbaki

DOI
https://doi.org/10.3390/ceramics6010030
Journal volume & issue
Vol. 6, no. 1
pp. 514 – 524

Abstract

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The paper presents the results on the development of an optical coating for a single-crystal ZnGeP2 substrate based on a selenide-oxide pair of materials (ZnSe/Al2O3). The obtained coating ensures the operation of OPO in the mid-IR range up to 5 μm wavelengths. The possibility of ZnSe sputtering by the IBS method is shown. The obtained optical coating has a high laser-induced damage threshold (LIDT) value at a 2097 µm wavelength: WoE=3.51 J/cm2 in energy density and WoP= 101 W/cm2 in power density at a 10 KHz pulse repetition frequency and a pulse duration of 35 ns. Thus, it is shown for the first time that the pair of materials ZnSe/Al2O3 can be used for the deposition of optical coatings by the IBS method with high LIDT values for ZnGeP2 optical elements operating in the mid-IR range.

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