Radio-frequency (RF) energy harvesting (EH) is emerging as a reliable and constantly available free energy source. The primary factor determining whether this energy can be utilized is how efficiently it can be collected. In this work, an RF EH system is presented. More particularly, we designed a dual-band RF to DC rectifier circuit at sub-6 GHz in the 5G bands, able to supply low-power sensors and microcontrollers used in agriculture, the military, or health services. The system operates at 3.5 GHz and 5 GHz in the 5G cellular network’s frequency band FR1. Numerical results reveal that the system provides maximum power conversion efficiency (PCE) equal to 53% when the output load (sensor or microcontroller) is 1.74 kΩ and the input power is 12 dBm.