Nature Communications (Feb 2018)

Revealing hole trapping in zinc oxide nanoparticles by time-resolved X-ray spectroscopy

  • Thomas J. Penfold,
  • Jakub Szlachetko,
  • Fabio G. Santomauro,
  • Alexander Britz,
  • Wojciech Gawelda,
  • Gilles Doumy,
  • Anne Marie March,
  • Stephen H. Southworth,
  • Jochen Rittmann,
  • Rafael Abela,
  • Majed Chergui,
  • Christopher J. Milne

DOI
https://doi.org/10.1038/s41467-018-02870-4
Journal volume & issue
Vol. 9, no. 1
pp. 1 – 9

Abstract

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Metal-oxide nanostructures are used in a range of light-driven applications, yet the fundamentals behind their properties are poorly understood. Here the authors probe photoexcited zinc oxide nanoparticles using time-resolved X-ray spectroscopy, identifying photocatalytically-active hole traps as oxygen vacancies in the lattice.