Nature Communications (Jan 2018)
Ultrasensitive reversible chromophore reaction of BODIPY functions as high ratio double turn on probe
- Dehui Hu,
- Tao Zhang,
- Shayu Li,
- Tianjun Yu,
- Xiaohui Zhang,
- Rui Hu,
- Jiao Feng,
- Shuangqing Wang,
- Tongling Liang,
- Jianming Chen,
- Lyubov N. Sobenina,
- Boris A. Trofimov,
- Yi Li,
- Jinshi Ma,
- Guoqiang Yang
Affiliations
- Dehui Hu
- Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences
- Tao Zhang
- Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences
- Shayu Li
- Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences
- Tianjun Yu
- Technical Institute of Physics & Chemistry, Key Laboratory of Photochemical Conversion & Optoelectronic Materials, University of Chinese Academy of Sciences, Chinese Academy of Sciences
- Xiaohui Zhang
- Technical Institute of Physics & Chemistry, Key Laboratory of Photochemical Conversion & Optoelectronic Materials, University of Chinese Academy of Sciences, Chinese Academy of Sciences
- Rui Hu
- Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences
- Jiao Feng
- Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences
- Shuangqing Wang
- Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences
- Tongling Liang
- Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences
- Jianming Chen
- Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences
- Lyubov N. Sobenina
- A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- Boris A. Trofimov
- A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- Yi Li
- Technical Institute of Physics & Chemistry, Key Laboratory of Photochemical Conversion & Optoelectronic Materials, University of Chinese Academy of Sciences, Chinese Academy of Sciences
- Jinshi Ma
- Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences
- Guoqiang Yang
- Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences
- DOI
- https://doi.org/10.1038/s41467-017-02270-0
- Journal volume & issue
-
Vol. 9,
no. 1
pp. 1 – 10
Abstract
BODIPY dyes, though widely explored, have not been pursued as chromophore reaction based chemical probes. Here, the authors synthesize a meso-naked BODIPY core flanked with two electron-withdrawing groups, which undergoes a reversible change in conjugated structure in the presence of base and functions as a dual signal and ultrahigh turn-on ratio chemical probe.