Crystals
(Apr 2020)
Hexnuclear Cadmium(II) Cluster Constructed from Tris(2-methylpyridyl)amine (TPA) and Azides
Franz A. Mautner,
Roland C. Fischer,
Bailey R. Williams,
Salah S. Massoud,
Nahed M. H. Salem
Affiliations
Franz A. Mautner
Institut für Physikalische and Theoretische Chemie, Technische Universität Graz, A-8010 Graz, Austria
Roland C. Fischer
Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 9/V, A-8010 Graz, Austria
Bailey R. Williams
Department of Chemistry, University of Louisiana at Lafayette, P.O. Box 43700 Lafayette, LA 70504, USA
Salah S. Massoud
Department of Chemistry, University of Louisiana at Lafayette, P.O. Box 43700 Lafayette, LA 70504, USA
Nahed M. H. Salem
Department of Chemistry, Faculty of Science, Alexandria University, P.O. Box 21511 Moharam Bey, Alexandria, Egypt
DOI
https://doi.org/10.3390/cryst10040317
Journal volume & issue
Vol. 10,
no. 4
Abstract
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A novel rare hexa nuclear cadmium(II)–azide cluster, [Cd6(TPA)4(μ3-1,1,3-N3)4(μ2-1,1-N3)6](ClO4)2·2H2O (1) was isolated and structurally characterized, in which the azide ligands reveal μ-1,1,3- and μ-1,1-N3 bridging modes.
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