Acta Crystallographica Section E (Dec 2011)

1,4-Bis[(2,2′:6′,2′′-terpyridin-4′-yl)oxy]butane

  • Matthew P. Akerman,
  • Craig D. Grimmer,
  • Varvara I. Nikolayenko,
  • Desigan Reddy

DOI
https://doi.org/10.1107/S1600536811050343
Journal volume & issue
Vol. 67, no. 12
pp. o3478 – o3479

Abstract

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The title compound, C34H28N6O2, has an inversion centre located at the mid-point of the central C—C bond of the diether bridging unit. The central pyridine rings of the terpyridyl units and the diether chain are co-planar: the maximum deviation from the 18-atom mean plane defined by the bridging unit and the central pyridyl ring is for the pyridyl N atom which sits 0.055 (1) Å above the plane. The dihedral angles between the terminal pyridine rings with this plane are 10.3 (1) and 37.6 (1)°, repectively. In the crystal, weak C—H...N interactions link the molecules into infinite chains parallel to the a axis.