Química Nova (Jan 2009)

A primeira lei da termodinâmica dos processos homogêneos The first law of homogeneous processes thermodynamics

  • Alessandro Ranulfo Lima Nery,
  • Adalberto Bono Maurizio Sacchi Bassi

DOI
https://doi.org/10.1590/s0100-40422009000200042
Journal volume & issue
Vol. 32, no. 2
pp. 522 – 529

Abstract

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Thermodynamics of homogeneous processes, which corresponds to the very special situation in thermodynamics of continuous media, is used to discuss the first law. An important part of this work is the exposition of some typical mathematical errors, frequently found in the traditional presentation of thermodynamics. The concepts of state and process functions are discussed, as well as reverse and reversible processes, temporality and its implications on thermodynamics, energy reservoirs and symmetry. Our proposal is to present the first law by using a time dependent viewpoint coherent with mechanics and the foundations of that viewpoint.

Keywords