Ionic liquid containing high-density polyethylene supported tungstate: a novel, efficient, and highly recoverable catalyst

Abstract

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Synthesis and catalytic application of polymeric-based nanocomposites are important subjects among researchers due to their high lipophilicity as well as high chemical and mechanical stability. In the present work, a novel nanocomposite material involving ionic liquid and high-density polyethylene supported tungstate (PE/IL-WO4=) is synthesized, characterized and its catalytic application is investigated. The coacervation method was used to incorporate 1-methyl-3-octylimidazolium bromide ([MOIm] [Br]) ionic liquid in high-density polyethylene, resulting in a PE/IL composite. Subsequently, tungstate was anchored on PE/IL to give PE/IL-WO4= catalyst. The PXRD, FT-IR, EDX, TGA, and SEM analyses were used to characterize the PE/IL-WO4= composite. This material demonstrated high catalytic efficiency in the synthesis of bioactive tetrahydrobenzo[a]xanthen-11-ones under green conditions. The recoverability and leching tests were performed to investigate the stability and durability of the designed PE/IL-WO4= catalyst under applied conditions.

Keywords

• polyethylene
• tetrahydrobenzo[a]xanthen-11-ones
• ionic liquid
• nanocomposite
• catalyst