Acta Crystallographica Section E (Sep 2008)

4,4′,5,5′-Tetramethyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol

  • Hoong-Kun Fun,
  • Reza Kia,
  • Chin Sing Yeap

DOI
https://doi.org/10.1107/S1600536808027220
Journal volume & issue
Vol. 64, no. 9
pp. o1854 – o1854

Abstract

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The title Schiff base compound, C23H30N2O2, has crystallographic twofold rotation symmetry. An intramolecular O—H...N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The imino group is coplanar with the benzene ring. The two benzene rings are almost perpendicular to each other, making a dihedral angle of 87.38 (4)°. In the crystal structure, neighbouring molecules are linked along the c axis by weak intermolecular C—H...O hydrogen bonds and are further packed into columns along the b axis, forming sheets which are parallel to the bc plane.