Poly[(μ3-3,5-diisopropyl-4H-1,2,4-triazolato-κ3N:N′:N′′)silver(I)]

Guo-Gen Cui; Xiao-Xi Yang; Jian-Ping Yang; Xiang Jiang

doi:10.1107/S1600536814008083

Acta Crystallographica Section E (May 2014)

Poly[(μ3-3,5-diisopropyl-4H-1,2,4-triazolato-κ3N:N′:N′′)silver(I)]

Guo-Gen Cui,
Xiao-Xi Yang,
Jian-Ping Yang,
Xiang Jiang

Affiliations

Guo-Gen Cui: School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
Xiao-Xi Yang: School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
Jian-Ping Yang: School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
Xiang Jiang: School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China

DOI: https://doi.org/10.1107/S1600536814008083
Journal volume & issue: Vol. 70, no. 5
pp. m189 – m189

Abstract

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In the polymeric title compound, [Ag(C8H14N3)]n, the AgI cation is coordinated by three N atoms from three 3,5-diisopropyl-1,2,4-triazolate anions in a T-shaped geometry. The AgI cation deviates from the coordination plane by 0.014 (1) Å and the N—Ag—N bond angles are 96.85 (11), 97.72 (10) and 165.39 (12)°. The triazolate anion bridges three AgI cations, forming a three-dimensional polymeric network.

Published in Acta Crystallographica Section E

ISSN: 1600-5368 (Online)
Publisher: International Union of Crystallography
Country of publisher: United Kingdom
LCC subjects: Science: Chemistry: Crystallography
Website: https://journals.iucr.org/e/

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