Nanomaterials (Oct 2023)

Nanoscatterer-Assisted Fluorescence Amplification Technique

  • Sylvain Bonnefond,
  • Antoine Reynaud,
  • Julie Cazareth,
  • Sophie Abélanet,
  • Massimo Vassalli,
  • Frédéric Brau,
  • Gian Luca Lippi

DOI
https://doi.org/10.3390/nano13212875
Journal volume & issue
Vol. 13, no. 21
p. 2875

Abstract

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Weak fluorescence signals, which are important in research and applications, are often masked by the background. Different amplification techniques are actively investigated. Here, a broadband, geometry-independent and flexible feedback scheme based on the random scattering of dielectric nanoparticles allows the amplification of a fluorescence signal by partial trapping of the radiation within the sample volume. Amplification of up to a factor of 40 is experimentally demonstrated in ultrapure water with dispersed TiO2 nanoparticles (30 to 50 nm in diameter) and fluorescein dye at 200 μmol concentration (pumped with 5 ns long, 3 mJ laser pulses at 490 nm). The measurements show a measurable reduction in linewidth at the emission peak, indicating that feedback-induced stimulated emission contributes to the large gain observed.

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