Atmospheric Chemistry and Physics (Dec 2011)

Projecting future HFC-23 emissions

  • B. R. Miller,
  • L. J. M. Kuijpers

DOI
https://doi.org/10.5194/acp-11-13259-2011
Journal volume & issue
Vol. 11, no. 24
pp. 13259 – 13267

Abstract

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A Reference Case (RC) scenario for emissions of HFC-23 from co-production during HCFC-22 manufacture over the next 25 years is presented. Offered as a template rather than a prediction, this model projects current production practices and existing abatement frameworks to yield insights into how atmospheric composition and radiative forcing might change with and without additional efforts to constrain HFC-23 emissions. <br></br> Assuming that no additional abatement measures are implemented, emissions for year 2035 in this Reference Case would rise to 24 ktonnes yr<sup>−1</sup>, (cf., 8.6 ktonnes yr<sup>−1</sup> in 2009), the atmospheric abundance of HFC-23 would rise to 50 ppt, which is a 121 % increase over the 2009 observed abundance, and HFC-23 would be expected to contribute a radiative forcing of 9 mW m<sup>−2</sup> (cf., 4 mW m<sup>−2</sup> in 2009). Under such a scenario, the HFC-23 emission growth rate would be a continuation of the historical trend of &sim;0.2 ktonnes yr<sup>−2</sup> until 2030, after which the growth is projected to quadruple as the Montreal Protocol phase-out of HCFC production for dispersive use concludes and HFC-23 thermal decomposition in the projects of the Clean Development Mechanism (CDM) comes to a scheduled end while growth in the production of HCFC-22 for feedstock use continues to climb with projected GDP growth. <br></br> Two opposite variations regarding the future renewal of CDM projects are examined for their impact on projected emissions and abundance, relative to the Reference Case scenario.