Catalysts (Apr 2022)

Sm-CeO<sub>2</sub>/Zeolite Bifunctional Catalyst for Direct and Highly Selective Conversion of Bioethanol to Propylene

  • Huan Jin,
  • Changxi Miao,
  • Yinghong Yue,
  • Chao Tian,
  • Weiming Hua,
  • Zi Gao

DOI
https://doi.org/10.3390/catal12040407
Journal volume & issue
Vol. 12, no. 4
p. 407

Abstract

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A series of Sm-CeO2/Beta composites with various Beta contents were prepared by an incipient impregnation method, followed by calcination at 650 °C. They were characterized by XRD, N2 adsorption, SEM, NH3-TPD, CO2-TPD and 27Al MAS NMR. The Sm-CeO2/Beta bifunctional catalysts exhibit eminent catalytic performances in the selective conversion of ethanol to propylene. In particular, the Sm-CeO2/10%Beta catalyst with 10% Beta zeolite gives the highest C3H6 yield of 59.3%. A good match between Sm-CeO2 and Beta accounts for its optimal result.

Keywords