Chiral polyoxometalate–cyclodextrin frameworks via Mn-mediated assembly: Enhanced stability and catalytic activity

Xiu-Xia Ding; Yun-Yue Yuan; Ya-Ge Zhang; Zhan-Guo Jiang; Cai-Hong Zhan

doi:10.26599/POM.2023.9140046

Polyoxometalates (Mar 2024)

Chiral polyoxometalate–cyclodextrin frameworks via Mn-mediated assembly: Enhanced stability and catalytic activity

Xiu-Xia Ding,
Yun-Yue Yuan,
Ya-Ge Zhang,
Zhan-Guo Jiang,
Cai-Hong Zhan

Affiliations

Xiu-Xia Ding: Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, Jinhua 321004, China
Yun-Yue Yuan: Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, Jinhua 321004, China
Ya-Ge Zhang: Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, Jinhua 321004, China
Zhan-Guo Jiang: ORCiD; Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, Jinhua 321004, China
Cai-Hong Zhan: ORCiD; Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, Jinhua 321004, China

DOI: https://doi.org/10.26599/POM.2023.9140046
Journal volume & issue: Vol. 3, no. 1
p. 9140046

Abstract

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The application of polyoxometalate (POM) as building blocks to construct chiral POM-based functionalized frameworks remains a long-standing challenge. In this study, we report a chiral assembly by blending inorganic POMs and organic cyclodextrin (α-CD) molecules on the basis of coordination interactions. {SiW12} anions connect with Mn ions (Mn2+) antiparallel to form a unique all-inorganic layer with significant voids. The similar α-CD layered structure fills the voids of the POM–Mn layers, which are interwoven to form an organic–inorganic hybrid, which is extended by Na+ ions to produce a three-dimensional framework. The stability, chiral separation, chiral catalysis, and proton conductivity of this composite framework are explored.

Published in Polyoxometalates

ISSN: 2957-9821 (Print); 2957-9503 (Online)
Publisher: Tsinghua University Press
Country of publisher: China
LCC subjects: Science: Chemistry: Inorganic chemistry
Website: https://www.sciopen.com/journal/2957-9821

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