Molecules (Mar 2023)

Mercury and Organic Pollutants Removal from Aqueous Solutions by Heterogeneous Photocatalysis with ZnO-Based Materials

  • Elisa Gaggero,
  • María José López-Muñoz,
  • Maria Cristina Paganini,
  • Amaya Arencibia,
  • Stefano Bertinetti,
  • Nieves Fernández de Paz,
  • Paola Calza

DOI
https://doi.org/10.3390/molecules28062650
Journal volume & issue
Vol. 28, no. 6
p. 2650

Abstract

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The removal of four Contaminants of Emerging Concern, namely bisphenol A, sulfamethoxazole, diclofenac and benzotriazole; two odorous compounds, geosmin and 2-methylisoborneol, frequently detected in recirculating aquaculture systems; and Hg(II) was investigated using ZnO-based materials doped or co-doped with Ce and Cu under simulated solar radiation. Photocatalysts were synthetized via a hydrothermal route and their efficiency was assessed by changing some operational parameters in different water matrices of increasing complexity. The mixture of contaminants was successfully degraded in just 1 h, while the complete mineralization was achieved in a few hours; experiments performed in an actual aquaculture water confirmed the efficiency and broad versatility of the synthesized materials.

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