Química Nova (Jan 2012)

Geração de mesoporos em zeólitas ZSM-5 e seus efeitos na conversão do etanol em olefinas

  • Ingryd Carvalho Alves,
  • Tâmara Lucia Pacheco de Mattos do Nascimento,
  • Cláudia de Oliveira Veloso,
  • Fátima Maria Zanon Zotin,
  • Cristiane Assumpção Henriques

DOI
https://doi.org/10.1590/S0100-40422012000800012
Journal volume & issue
Vol. 35, no. 8
pp. 1554 – 1559

Abstract

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Developing mesoporosity in HZSM-5 zeolites is an alternative for improving their catalytic performance on chemical reactions. In this work, alkaline and thermal treatments were used to produce mesoporosity. These treatments increased mesoporous area and volume. They also influenced the acid properties of the samples. Concerning catalytic performance, treatments modified reaction product distribution. Whereas alkaline treatment favored formation of olefins and increased propene ratio in the beginning of the reaction, thermal treatment resulted in formation of only ethylene due to the low acidity of the sample.

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