Catalysts (Jul 2021)

Effect of Temperature, Syngas Space Velocity and Catalyst Stability of Co-Mn/CNT Bimetallic Catalyst on Fischer Tropsch Synthesis Performance

  • Omid Akbarzadeh,
  • Solhe F. Alshahateet,
  • Noor Asmawati Mohd Zabidi,
  • Seyedehmaryam Moosavi,
  • Amir Kordijazi,
  • Arman Amani Babadi,
  • Nor Aliya Hamizi,
  • Yasmin Abdul Wahab,
  • Zaira Zaman Chowdhury,
  • Suresh Sagadevan

DOI
https://doi.org/10.3390/catal11070846
Journal volume & issue
Vol. 11, no. 7
p. 846

Abstract

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The effect of reaction temperature, syngas space velocity, and catalyst stability on Fischer-Tropsch reaction was investigated using a fixed-bed microreactor. Cobalt and Manganese bimetallic catalysts on carbon nanotubes (CNT) support (Co-Mn/CNT) were synthesized via the strong electrostatic adsorption (SEA) method. For testing the performance of the catalyst, Co-Mn/CNT catalysts with four different manganese percentages (0, 5, 10, 15, and 20%) were synthesized. Synthesized catalysts were then analyzed by TEM, FESEM, atomic absorption spectrometry (AAS), and zeta potential sizer. In this study, the temperature was varied from 200 to 280 °C and syngas space velocity was varied from 0.5 to 4.5 L/g.h. Results showed an increasing reaction temperature from 200 °C to 280 °C with reaction pressure of 20 atm, the Space velocity of 2.5 L/h.g and H2/CO ratio of 2, lead to the rise of CO % conversion from 59.5% to 88.2% and an increase for C5+ selectivity from 83.2% to 85.8%. When compared to the other catalyst formulation, the catalyst sample with 95% cobalt and 5% manganese on CNT support (95Co5Mn/CNT) performed more stable for 48 h on stream.

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