Studies of carboxylated nitrile butadiene rubber/butyl reclaimed rubber (XNBR/BRR) blends for shoe soles application

Abstract

Rising environmental issues and huge disposal of rubber waste have resulted in an increased interest in the usage of reclaimed rubber (RR) to produce sustainable and environmental friendly applications. In this study, incorporation of butyl reclaimed rubber into carboxylated nitrile butadiene rubber (XNBR/BRR) was carried out where the loadings of each XNBR and BRR were varied. The rubber was cured with sulphur during the melt mixing using a two-roll mill. This study is aimed to investigate the applied BRR loading towards the physical and mechanical properties of the XNBRcompounds. The results appeared that the optimum cure time (T90) increased and curing rate index (CRI) showed that a faster curing reaction with the increase in the content of BRR where the T90 had an increment of 89% while the CRI was faster by 89%. As for the crosslink density which indicates the density of chains or segments in polymer network, it decreased about 20% with increasing level of BRR. Also, the compression set which refers to the ability of rubber to resist permanent deformation, had an increase of 73% as the loading ratio of BRR increased. These results were obtained due to the low molecular weight of the BRR where the high shear and temperature during the reclamation process severely breaks down the molecular chains of the BRR into shorter segments. With the results obtained, it is shown that reclaimed rubber has the potential for further development and could increase the interest of researchers all around the world in the incorporation of reclaimed rubber for footwear application.

Keywords

• rheological properties
• swelling
• compression set
• carboxylated nitrile butadiene rubber/butyl reclaimed rubber blends
• rubber