Stable Radical Isoporphyrin Copolymer Prepared with Di(phenylphosphane)
Yiming Liang,
Antoine Bonnefont,
Vasilica Badets,
Corinne Boudon,
Michel Goldmann,
Guillaume Diot,
Sylvie Choua,
Nolwenn Le Breton,
Laurent Ruhlmann
Affiliations
Yiming Liang
Zhengzhou Research Base, National Key Laboratory of Cotton Bio-Breeding and Integrated Utilization, School of Agricultural Sciences, Zhengzhou University, Zhengzhou 450001, China
Antoine Bonnefont
Institut de Chimie, UMR CNRS 7177, Université de Strasbourg, 4 Rue Blaise Pascal, CS 90032, F-67081 Strasbourg Cedex, France
Vasilica Badets
Institut de Chimie, UMR CNRS 7177, Université de Strasbourg, 4 Rue Blaise Pascal, CS 90032, F-67081 Strasbourg Cedex, France
Corinne Boudon
Institut de Chimie, UMR CNRS 7177, Université de Strasbourg, 4 Rue Blaise Pascal, CS 90032, F-67081 Strasbourg Cedex, France
Michel Goldmann
Institut des Nanosciences de Paris, UMR CNRS 7588, Sorbonne Université, 4 Place Jussieu, Boîte Courrier 840, F-75252 Paris, France
Guillaume Diot
Institut des Nanosciences de Paris, UMR CNRS 7588, Sorbonne Université, 4 Place Jussieu, Boîte Courrier 840, F-75252 Paris, France
Sylvie Choua
Institut de Chimie, UMR CNRS 7177, Université de Strasbourg, 4 Rue Blaise Pascal, CS 90032, F-67081 Strasbourg Cedex, France
Nolwenn Le Breton
Institut de Chimie, UMR CNRS 7177, Université de Strasbourg, 4 Rue Blaise Pascal, CS 90032, F-67081 Strasbourg Cedex, France
Laurent Ruhlmann
Institut de Chimie, UMR CNRS 7177, Université de Strasbourg, 4 Rue Blaise Pascal, CS 90032, F-67081 Strasbourg Cedex, France
Two diphosphanes with variable-length ligands tested as nucleophiles to prepare isoporphyrin copolymers in the presence of ditolylporphyrin of zinc (ZnT2P) prevented the oxidation of the diphosphine ligand. This paper demonstrates the power of this approach and describes the photoelectrocatalytic properties. The obtained copolymers were characterized by UV–vis spectroscopy, X-ray photoelectron spectroscopy, atomic force micrograph (AFM), EQCM (Electrochemical Quartz Cristal Microbalance) and electrochemistry. Their impedance properties (EIS) were studied and their photovoltaic performances were also investigated by photocurrent transient measurements under visible light irradiation.
