Acta Crystallographica Section E (Mar 2008)

{N,N-Bis[2-(trimethylsilylamino)ethyl]-N′-(trimethylsilyl)ethane-1,2-diaminato(3–)-κ4N}methylzirconium(IV)

  • Rory Waterman,
  • Joseph M. Tanski,
  • Samantha N. MacMillan

DOI
https://doi.org/10.1107/S160053680800425X
Journal volume & issue
Vol. 64, no. 3
pp. m477 – m477

Abstract

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The title compound, [Zr(CH3)(C15H39N4Si3)], is a unique example of a triamidoamine-supported zirconium–methyl complex that crystallized as a monomer with trigonal–bipyramidal geometry at zirconium, featuring a Zr—C bond of 2.2963 (16) Å.