Acta Crystallographica Section E (Mar 2008)
{N,N-Bis[2-(trimethylsilylamino)ethyl]-N′-(trimethylsilyl)ethane-1,2-diaminato(3–)-κ4N}methylzirconium(IV)
Abstract
The title compound, [Zr(CH3)(C15H39N4Si3)], is a unique example of a triamidoamine-supported zirconium–methyl complex that crystallized as a monomer with trigonal–bipyramidal geometry at zirconium, featuring a Zr—C bond of 2.2963 (16) Å.