Acta Crystallographica Section E (Jan 2012)

1-Benzoyl-3-(2,4,5-trichlorophenyl)thiourea

  • M. Khawar Rauf,
  • Masahiro Ebihara,
  • Amin Badshah,
  • Imtiaz-ud-Din

DOI
https://doi.org/10.1107/S1600536811052780
Journal volume & issue
Vol. 68, no. 1
pp. o119 – o119

Abstract

Read online

The benzene and phenyl rings in the title compound, C14H9Cl3N2OS, form a dihedral angle of 40.98 (6)°. The molecule exists in the thione form with typical thiourea C—S [1.666 (2) Å] and C—O [1.227 (3) Å] bond lengths as well as shortened C—N bonds [1.345 (3) and 1.386 (2) Å]. An intramolecular N—H...O hydrogen bond stabilizes the molecular conformation. In the crystal, pairs of N—H...S hydrogen bonds link the molecules into centrosymmetric dimers.