IUCrData (Apr 2023)

(23R,231S,25S)-231,26-Epoxy-23-ethylfurost-20(22)-en-3β-ol

  • Gabriel Guerrero-Luna,
  • María-Guadalupe Hernández-Linares,
  • Maura Cárdenas García,
  • Sylvain Bernès

DOI
https://doi.org/10.1107/S2414314623003449
Journal volume & issue
Vol. 8, no. 4
p. x230344

Abstract

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The title compound, C29H46O3, is a steroid synthesized through a rearrangement of a sarsasapogenin derivative in acidic medium. The newly formed ring F is a tetrahydro-2H-pyran heterocycle substituted by two methyl groups placed in equatorial positions. This ring displays a chair conformation, while dihydrofuran ring E, to which it is bonded, has an envelope conformation. The molecules are associated by weak O—H...O hydrogen bonds to form chains running in the [101] direction in the crystal.

Keywords