Impacts of non-ideality and the thermodynamic pressure work term <i>p</i>Δ<i>v</i> on the surface energy balance

Abstract

Present-day eddy-covariance-based methods for measuring the energy and mass exchange between the earth's surface and the atmosphere often do not close the surface energy balance. Frequently the turbulent energy fluxes (sum of sensible and latent heat) underestimate the available energy (net incoming radiation minus the soil conductive heat flux) by 10 % to 20 % or more. Over the last 3 or 4 decades several reasons for this underestimation have been proposed, but nothing completely definitive has been found. This study examines the contribution of two rarely discussed aspects of atmospheric thermodynamics to this underestimation: the non-ideality of atmospheric gases and the significance the water vapor flux has for the sensible heat flux, an issue related to the pressure work term pΔv. The results were not unexpected; i.e., these effects are too small to account for all of the imbalance between the sum of the turbulent fluxes and the available energy. Together they may contribute 1 %–3 % of the difference (or 10 % to 15 % of the percentage imbalance).