Valorizing biomass waste glycerol to fuel additive at room temperature using a nanostructured WO3/Nb2O5 catalyst

Abstract

We developed a nanostructured catalyst consisting of WO3 nanoparticles and Nb2O5 nanorods for efficient glycerol acetalization to produce a fuel additive (solketal) at room temperature. Particularly, the WO3/Nb2O5 nanocatalyst calcined at 400 °C (WO3/Nb2O5–4) contains W5+ species and optimum acid sites, which enhanced glycerol conversion (92.3%) with 95.6% of solketal selectivity at room temperature. The structure stability of the WO3/Nb2O5–4 catalyst during the reaction is showcased by hot-filtration study and XRD/XPS characterization. However, the inadequate regeneration of the Brønsted acid sites led to a gradual decrease in the recyclable activity of the WO3/Nb2O5–4 catalyst.

Keywords

• Room-temperature glycerol acetalization
• Fuel additive
• WO3/Nb2O5 nanomaterial
• Brønsted-Lewis acid sites, W5+ species