Acta Crystallographica Section E: Crystallographic Communications (Nov 2024)

Crystal structure of a hydrogen-bonded 2:1 co-crystal of 4-nitrophenol and 4,4′-bipyridine

  • Angela Gotingco,
  • Merary Villanueva Contreras,
  • Jeanette A. Wolfarth,
  • S. Chantal E. Stieber,
  • Zoe Y. Marr

DOI
https://doi.org/10.1107/S205698902400971X
Journal volume & issue
Vol. 80, no. 11
pp. 1135 – 1137

Abstract

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In the title compound, C10H8N2·2C6H5NO3, 4-nitrophenol and 4,4′-bipyridine crystallized together in a 2:1 ratio in the space group P21/n. There is a hydrogen-bonding interaction between the nitrogen atoms on the 4,4′-bipyridine molecule and the hydrogen atom on the hydroxyl group on the 4-nitrophenol, resulting in trimolecular units. This structure is a polymorph of a previously reported structure [Nayak & Pedireddi (2016). Cryst. Growth Des. 16, 5966–5975], which differs mainly due to a twist in the 4,4′-bipyridine molecule.

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